First...anything to reduce your heat transfer... Awnings, shades, insulated foil, slide toppers, window film.
Secondly...I've had to deal with what you're experiencing. There are a few different approaches...each with advantages and disadvantages.
1). 30A to 50A conversion. This changes out your distribution box and converter, and feed wiring...to allow for 50A service. When that is done, you can add a second rooftop unit. Two rooftop units will make a huge difference in cooling. We cool a 40ft Class A with two 15K units.
2) Portable a/c... with our fifth wheel...we used a portable A/C unit and ducted the exhaust out a window. I made a filler for that window when slide open, which also had an electrical pigtail. It allowed for a 12awg extension cord to be connected directly to a 20a outlet in the pedastle...and the portable A/C plugged into that,. It was only an 11,000 BTU unit,,,but added sufficient extra cooling in our 30ft fifth wheel to get us thru with the OEM 13.5K roof unit. I have also seen folks add a mini-split...which plugs in separately to the pedestal. If you have a place to mount it...they are super efficient.
3) Adding solar and Inverter... This requires a lot of additional items...and probably not advised for most wiring layouts. It requires a robust Inverter/Battery setup...as most of your coach will be running off of this during the day. A combined inverter/charger with pass thru is a must. What you do is during the day...the solar/battery/inverter is setup to power the lights, outlets, and electrical appliances that are within the capability of the inverter. The only thing running off of shore power during the day is the A/C units. You can run two rooftop units on 30A IF...IF...IF... (big IF)...you have all your other A/C loads running on the Solar/Battery/Inverter...and BOTH A/C unit's have a common control unit, and MicroAir Easy Start unit's installed. I do this a lot with our Coach. It's easy for me...I just set my inverter to not use shore power unless the battery drops below a certain state of charge. During the day, with solar providing plenty of watts...the batteries stay fully charged. So my solar is running outlets, tvs, water pump, microwave, etc... This leaves my shore connection of 30a dedicated to running my rooftop units. I have two 15KBTU Heat Pumps...and the common control is designed NOT to start the units at the same time. The MicroAir Easy start prevents the overcurrent protection from tripping due to high locked rotor amp spikes. I easily run them both on a 30A shore power connection. You would need to see if your distribution box has room for a second 20A breaker to add a second A/C unit. If it has it's own converter...you would need to disable that...so it's not hoarding the shore power. Let the solar do what your converter was doing...by charging the batteries, and suppling dc needs...as well as limited inverter ac loads.